UH ORGANIC CHEMISTRY
Brief Summary
Monosub Electrophilic Aromatic Substitution (EAS)
Halogenation
Nitration
Sulfonation
Friedel-Craft Alkylation & Acylation
EAS Mechanism (All 5 EAS)
Alternative F-C Alkylation
Alkene + HF
alcohol + BF3
F-C Limitations
Carbocations, EWGs, Amine reactions, Polyalkylation
Regioselectivity of EAS
Special Case: Halogens
Mechanisms & Kinetics of EAS
Activating vs Deactivating Groups
Donating vs Withdrawing Groups
Disubstituted EAS
NOTE: Simple and advanced only
Donating: Ortho / Para
Steric hindrance factor
Withdrawn: Meta
Nucleophilic Aromatic Substitution
A/E NAS (Exist a EWGs of a halogen in O-/P-
E/A NAS (Absent of EWG of a halogen.
Other Benzylic Reactions
Addition, Birch Reduction, Side Chains (Oxidation, Radial Halogenation).
Phenol Reactions
to alkoxide
to ester
Benzoquinone
Salicylic Acid -- Aspirin Synthesis
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Home
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Lecture Course Navigation
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Laboratory Info
Orgo I Lab Contents
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Lecture Notes