UH ORGANIC CHEMISTRY
Chapter 15: Conjugate Systems
Brief Summary
- Type of dienes
- Conjugated (FOCUS), Isolated, Cummulated
- Stability of conjugation
- Explanation
- Reactivity
- Mechanism
- Reactivity
- Explanation
- Product yield:
- Temperature Dependance
- Kinetic vs Thermodynamic Products
- Transition state vs product stability
- Kinetic vs Thermodynamic Products
- Temperature Dependance
- Allylic Reaction
- Conjugation influence of reactivity
- Diels-Alder Reaction
- General model + mechanism
- Anatomy:
- Dienophile (with Withdrawn Groups)
- Stereochemistry Preserve
- Diene (with Donating Groups)
- Stereochemistry Influence
- Dienophile (with Withdrawn Groups)
- The Endo Rule
- Unsymmetrical Product
- Mechanism Explanation
- Favoring 1,2 OR 1,4 addition
- Mechanism Explanation
- UV-VIS Spectroscopy
- Conjugation influence & Fisher Rule